In a large bowl, whisk together flour, cocoa powder, baking soda, baking powder, sugar, and salt.
In another bowl, whisk together oil, buttermilk, eggs, and vanilla.
Slowly pour the wet ingredients into the dry ingredients. Mix until just combined—don’t overmix.
Stir in the hot coffee water mixture until the batter is smooth. The batter will be runny; that’s normal.